Album was composed by and was released on September 18, 2007. Soundtrack consists of 41 tracks tracks with duration over more than hour. Album was released by Shout! Factory LLC, 2042-A Armacost Ave., Los Angeles, CA 90025.
CD 1
| 1 | "The Simpsons" Main Title ThemeThe Alf Clausen Orchestra | 01:21 |  |
| 2 | TestifyThe Simpsons | 01:40 | |
| 3 | The Very Reason That I LiveThe Simpsons | 02:27 | |
| 4 | He's the Man (feat. Shawn Colvin)The Simpsons | 02:00 | |
| 5 | Stretch Dude and Clobber GirlThe Simpsons | 00:44 | |
| 6 | "The Simpsons" End Credits ThemeLos Lobos | 00:40 | |
| 7 | Ode to BransonThe Simpsons | 01:59 | |
| 8 | Sold SeparatelyThe Simpsons | 00:45 | |
| 9 | Island of SirensThe Simpsons | 00:51 | |
| 10 | They'll Never Stop the SimpsonsThe Simpsons | 01:15 | |
| 11 | You're a Bunch of StuffThe Simpsons | 01:49 | |
| 12 | What Do I Think of the Pie?The Simpsons | 00:37 | |
| 13 | Baby Stink BreathThe Simpsons | 00:29 | |
| 14 | Tastes Like LibertyThe Simpsons | 01:12 | |
| 15 | JellyfishThe Simpsons | 01:39 | |
| 16 | Homer & Marge (feat. "Weird Al" Yankovic)The Simpsons | 01:47 | |
| 17 | Everybody Hates Ned Flanders MedleyThe Simpsons | 04:09 | |
| 18 | I Love to WalkThe Simpsons | 01:25 | |
| 19 | Marjorie (feat. Jackson Browne)The Simpsons | 02:17 | |
| 20 | "The President Wore Pearls" Medley: A Vote for a Winner / I Am Their Queen / Skinner's Evil Plan / A Tango Takes Two / Smart Girl Six Three / The President Wore Pearls End CreditsThe Simpsons | 05:59 | |
| 21 | Glove Slap (feat. The B-52s)The Simpsons | 01:22 | |
| 22 | O Pruny NightThe Simpsons | 00:45 | |
| 23 | America (I Love This Country)The Simpsons | 01:05 | |
| 24 | America RulesThe Simpsons | 01:23 | |
| 25 | Welcome to Moe'sThe Simpsons | 01:15 | |
| 26 | We Are the JockeysThe Simpsons | 01:35 | |
| 27 | Song of ShelbyvilleThe Simpsons | 01:09 | |
| 28 | "A Star Is Torn" Medley: I'm Talkin' Springfield / My Kitty Died / Always My Dad / A Privileged BoyThe Simpsons | 04:29 | |
| 29 | Who Wants a Haircut? (feat. Baha Men)The Simpsons | 01:06 | |
| 30 | "My Fair Laddy" Medley: Adequate / Not On My Clothes / Indoors All Night / Longing for the Shack / My Fair Laddy End CreditsThe Simpsons | 06:23 | |
| 31 | Springfield BlowsThe Simpsons | 00:34 | |
| 32 | "King of Cats" Itchy & Scratchy Medley: Tune-Up / King of Cats Opening / Two Days, Two Circles / Slices of Life / It's Symbiotic / Knives FinaleThe Simpsons | 03:39 | |
| 33 | LadyThe Simpsons | 01:34 | |
| 34 | You Make Me LaughThe Simpsons | 00:25 | |
| 35 | Lady Riff (feat. Ricky Gervais)The Simpsons | 00:34 | |
| 36 | Poppa, Can You Hear Me?The Simpsons | 00:48 | |
| 37 | "Yokel Chords" Medley: Oh, How Do We? / Motivate Them / Cultural Things Experience / Moonshine DrinkersThe Simpsons | 03:50 | |
| 38 | Hullaba LulaThe Simpsons | 00:51 | |
| 39 | Song of the Wild BeastsThe Simpsons | 00:50 | |
| 40 | Dancing Workers' SongThe Simpsons | 01:14 | |
| 41 | Oldies and NudiesThe Simpsons | 01:11 | |
