Album was composed by and was released on December 17, 2007. Soundtrack consists of 12 tracks tracks with duration over about 45 minutes. Album was released by Polydor Ltd.
CD 1
| 1 | Theme to St. TriniansGirls Aloud | 04:29 |  |
| 2 | TroubleCast of St. Trinian's | 03:32 | |
| 3 | Love Is In the AirRupert Everett & Colin Firth | 03:49 | |
| 4 | Don't Give UpNoisettes | 02:29 | |
| 5 | Nine2fiveThe Ordinary Boys & Lady Sovereign | 03:02 | |
| 6 | If I Can't DanceSophie Ellis-Bextor | 03:23 | |
| 7 | Teenage KicksRemi Nicole | 02:25 | |
| 8 | SanctuaryGabriella Cilmi | 03:27 | |
| 9 | Love Is a Many Splendored ThingThe Four Aces & Al Alberts | 02:57 | |
| 10 | 3 Spoons of SugaSugababes | 03:50 | |
| 11 | On My Way to SatisfactionGirls Aloud | 04:05 | |
| 12 | Defenders of Anarchy (The St. Trinians School Song)Cast of St. Trinian's | 03:47 | |
