Music: Norihito Sumitomo (expect track1, 12, 25, 26)
M-01
Vocals: HITOMI
Compose: Go Misawa
Arranger: Masaki Iehara
Lyricist: Tokyo Movie Kikakubu
M-12
Composer: Go Misawa
Arranger: Norihito Sumitono
M-26
Composer: Tetsuro Oda
Arranger: Daisuke Kahara
Lyricist: Tetsuro Oda
Album was composed by Go Misawa / Norihito Sumitomo / Norihito Sumitomo / Tetsuro Oda and was released on September 22, 2004. Soundtrack consists of 26 tracks tracks with duration over more than hour. Album was released by Columbia Music Entertainment.
CD 1
| 1 | エースをねらえ! | 03:17 | |
| 2 | 岡ひろみのテーマ | 02:22 | |
| 3 | 憧れのイニシャルR.R. | 01:44 | |
| 4 | 学園生活 | 02:23 | |
| 5 | TRAINING 1 | 01:52 | |
| 6 | RALLY 1 | 04:08 | |
| 7 | 敗北 | 01:46 | |
| 8 | ひろみの涙 | 02:50 | |
| 9 | お蝶夫人のテーマ | 01:41 | |
| 10 | TRAINING 2 | 02:02 | |
| 11 | GOOD FIGHT! | 01:54 | |
| 12 | エースをねらえ! -Piano Version- | 02:02 | |
| 13 | マキとゴエモンと... | 03:30 | |
| 14 | ディア・フレンド | 01:57 | |
| 15 | 才能 | 01:53 | |
| 16 | 恋するひろみ | 02:15 | |
| 17 | 回想と不安 | 03:47 | |
| 18 | プレッシャー | 02:12 | |
| 19 | 夢を託して | 02:01 | |
| 20 | 宗方 仁のテーマ | 02:19 | |
| 21 | RALLY 2 | 02:02 | |
| 22 | 緊張 | 01:58 | |
| 23 | ACE! | 01:42 | |
| 24 | 「岡、エースをねらえ!」 | 01:36 | |
| 25 | エースをねらえ! -Instrumental Version- | 01:55 | |
| 26 | 愛のために。 -オルゴール Version- | 02:52 | |
